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X-Rays - Another Form of Light

Emission and Absorption Lines

Chandra High Energy Transmission Grating Spectrum of NGC 4151
Chandra High Energy Transmission Grating Spectrum of NGC 4151
When a free-ranging electron is accelerated by the electric field of a proton or charged atom (ion), the photons emitted can have a wide range of energies that depends on how fast the electrons are moving and how much they are accelerated. The distribution of photon energies due to this process is called a continuous spectrum, and can be graphed as a smooth curve.

In contrast, if the electron is in orbit around the nucleus of a neutral or charged atom, the spectrum is a series of sharp peaks, or lines. This happens because the orbits of electrons in an atom are strictly regulated by the rules of quantum theory. These orbits, or more accurately, energy states, are separated by a specific amount of energy, just as stairs are separated by a specific height. Just as you cannot move to a position between stair steps, an electron in an atom cannot move to a position between energy states. The atoms for each element, such as oxygen, carbons, etc., have their own unique sets of energy states.

Normally the electrons in atoms are in the lowest energy state, at the bottom of the stairs. But if the atom has been excited by a collision with a free electron, another atom, or a photon, the lowest energy level will be unoccupied. One of the orbiting electrons will quickly jump down to this level, releasing energy in the form of a photon of a specific energy. These photons give rise to an emission line in the spectrum. A hot gas composed of many atoms will give off a spectrum composed of many emission lines due to the various elements that are present in the gas.

Atomic Emission
Atomic Emission

The opposite process can also occur. If a stream of photons encounters a gas, those photons whose energy corresponds to energy levels in an atom a step will be absorbed by the atom. This process gives rise to a series of absorption lines in the gas.

Careful studies of the energies of the photons emitted or absorbed by an atom of a particular element give a blueprint for the energy states of that atom. Knowing this blueprint, or energy spectrum, astronomers can look for it in the radiation from stars and gas, and determine the amount of each element present. In this way, astronomers have determined that stars are mostly made of hydrogen, with a mixture of helium and traces of heavier elements such as carbon, nitrogen, oxygen, and so on.
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